1-(((6-(Methoxycarbonyl)-5-oxononan-4-yl)oxy)carbonyl)cyclopropane-1-carboxylic Acid
نویسندگان
چکیده
Here, we first report the 2′-acyloxy-1,3-dicarbonyl compound construction in a three-component oxidative reaction of alkyl ketene dimer with cyclic diacyl peroxide and trimethyl orthoformate. The discovered synthesis allows us to form 2′-functionalized 1,3-dicarbonyl compounds instead common 2-functionalized moiety. between 4-butylidene-3-propyloxetan-2-one cyclopropyl malonoyl proceeds presence trifluoroacetic acid orthoformate at 120 °C for 1 h. synthesized was characterized by NMR spectroscopy, mass spectrometry, IR spectroscopy.
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ژورنال
عنوان ژورنال: Molbank
سال: 2023
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1651